Tango in the Night - Fleetwood Mac when I was in Uni in the late 80s . Only bought CD's since then.
First vinyl I bought myself Madness - Driving in My Car, as opposed to first vinyl bought for me be my sister (who used to buy the ones she like for me) which was Nobody does it Better - Carly Simon. Having said than I do now think it's one of the better Bond Themes.