That's indeed a very beautiful city, definitely worth visiting. Unfortunately, I've only been to Kiev once. It was the summer 1 year before Euro. The city centre's architecrute, the sights from the hills near the river, etc, are all amazing. Not sure how would it look like during winter, but I'd like to catch up what I didn't manage to see last time I was there.
From the football side though, which isn't that important in such kinds of trips, I'd expect some classics from pellers - something like a boring match with deffensive problemes and mistakes where we would still try to play for a draw.
P.S. I'm wondering how many City fans are expected to be at the away end?