There is an element of truth in that. I can remember doing a penalty shootout in training for my Saturday team, I won so I got to take them when ever we first had one. Shit out and blasted it over, I've never taken one again. Shit example, but it does show you need a cool ahead rather than someone with the most ability.
Are you Alan Harper - that is exactly what happened to him.
Kompany has a 100% record for City taking pens, along with Yaya and Navas.
Some less notable recent 100% records:
Milner
Evans (3 scored btw)
SWP
Petrov
Hamman
Corluka